( )-Caryolan-1-ol synthase - definizione. Che cos'è ( )-Caryolan-1-ol synthase
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Cosa (chi) è ( )-Caryolan-1-ol synthase - definizione

CHEMICAL COMPOUND
(Z)-3-hexen-1-ol; Leaf alcohol; (Z)-3-Hexen-1-ol; 3-hexen-1-ol; 3-Hexen-1-ol; Hexenol; Cis-3-hexen-1-ol; (Z)-Hex-3-en-1-ol; Cis-3-hexenol

(+)-Caryolan-1-ol synthase         
CLASS OF ENZYMES
(+)-caryolan-1-ol synthase; EC 3.7.1.15; (+)-beta-caryophyllene hydrolase (cyclizing, (+)-caryolan-1-ol-forming); (+)-beta-caryophyllene hydrolase; EC 4.2.1.138; (+)-β-caryophyllene hydrolase (cyclizing, (+)-caryolan-1-ol-forming)
(+)-Caryolan-1-ol synthase (, GcoA) is an enzyme with systematic name (+)-β-caryophyllene hydrolase (cyclizing, (+)-caryolan-1-ol-forming). This enzyme catalyses the following chemical reaction
PTGS1         
MAMMALIAN PROTEIN FOUND IN HOMO SAPIENS
COX-1; Prostaglandin-endoperoxide synthase 1; PCOX1; Pcox1; PGHS-1; Pghs-1; PGHS1; Pghs1; Phs1; PTGHS; Ptghs; Cyclooxygenase-1; Cox-1; PTGS1 (gene); Cycloxygenase-1
Cyclooxygenase 1 (COX-1), also known as prostaglandin G/H synthase 1, prostaglandin-endoperoxide synthase 1 or prostaglandin H2 synthase 1, is an enzyme that in humans is encoded by the PTGS1 gene. In humans it is one of two cyclooxygenases.
1-Aminocyclopropane-1-carboxylate synthase         
  • Tyrosine and PLP stabilized 3C-Ring formation.
  • ACC Synthase Complex with PLP
  • ACC Synthase Complex with PLP: Catalytic Domain
  • Lys to SAM Imine Exchange.
  • Formation of the Quinonoid Intermediate.
  • Formation of the ACS-PLP Schiff Base.
  • Lysine and Tyrosine Residues in the Substrate Binding Site
CLASS OF ENZYMES
EC 4.4.1.14; S-adenozil-L-metionin methylthioadenosine-lyase (1-aminocyclopropane-1-carboxylate-forming); 1-aminocyclopropane-1-carboxylate synthase
Aminocyclopropane-1-carboxylic acid synthase (ACC synthase, ACS) () is an enzyme that catalyzes the synthesis of 1-Aminocyclopropane-1-carboxylic acid (ACC), a precursor for ethylene, from S-Adenosyl methionine (AdoMet, SAM), an intermediate in the Yang cycle and activated methyl cycle and a useful molecule for methyl transfer. ACC synthase, like other PLP dependent enzymes, catalyzes the reaction through a quinonoid zwitterion intermediate and uses cofactor pyridoxal phosphate (PLP, the active form of vitamin B6) for stabilization.

Wikipedia

Cis-3-Hexen-1-ol

cis-3-Hexen-1-ol, also known as (Z)-3-hexen-1-ol and leaf alcohol, is a colorless oily liquid with an intense grassy-green odor of freshly cut green grass and leaves. It is produced in small amounts by most plants and it acts as an attractant to many predatory insects. cis-3-Hexen-1-ol is a very important aroma compound that is used in fruit and vegetable flavors and in perfumes. The yearly production is about 30 tonnes.

cis-3-Hexen-1-ol is an alcohol and its esters are also important flavor and fragrance raw materials. The related aldehyde cis-3-hexenal (leaf aldehyde) has a similar and even stronger smell but is relatively unstable and isomerizes into the conjugated trans-2-hexenal.

This compound has been recognized as a semiochemical involved in mechanisms and behaviors of attraction in diverse animals such as insects and mammals. However, there is no scientific evidence of its aphrodisiac effects in humans. The popular Mexican alcoholic beverage, mezcal, is found to have enhanced concentrations of this compound when a maguey worm is served in the glass.